Theory of Impurity-Induced Infrared Absorption in Alkali Halide Crystals
نویسندگان
چکیده
منابع مشابه
Clustering of divalent cation-vacancy pairs in alkali halide crystals
The analysis of experimental results of the clustering of divalent cation-vacancy pairs by Unger and Perlman is shown here to be unable to distinguish between their model of dimer formation and the earlier model of' Dryden for trimer formation under the conditions where it has been applied. In general, experimental results appear to correspond to overall third order kinetics in the pre-plateau ...
متن کاملIMPURITY [NDUCED FAR INFRARED ABSORPTION OF CsI CRYSTALS L.GENZEL, W. PRETTL and E.SIEP
In perfect alkali halide crystals only the transverse optic phonons of zero wave vector absorb far infrared radiation in first order. The introduction of impurities in the lattice removes the translational invariance and almost all phonons become optically active. In addition to the absorption at the reststrahlen frequency, impurity induced absorption appears in the phonon band region and somet...
متن کاملRelaxation processes of the triplet state of self-trapped excitons in alkali-halide crystals
— The spin lattice relaxation, radiative and microwave excitation processes of the triplet self-trapped exciton hâve been studied in alkali chlorides and bromides by measuring the transient response of the X-ray excited luminescence to résonant puise microwave. The model is applied to magnetic circular polarization data. The symmetry of dominant exciton-phonon coupling are discussed.
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Alkali halides and alkaline earth halides are strongly ionic compounds that solidify as crystals. The name for the alkali elements (Li, Na, K, Rb and Cs) comes from the Arabic word alqili (ashes of the salt-wort plant that was once used as a source of sodium and potassium for making glass from sand). The name for the halogen elements (F, Cl, Br, I—and the rare radioactive element astatine) come...
متن کاملMany-body contributions to the intermolecular potential in alkali halide crystals and clusters
SCFMO calculations have been made on lithium fluoride clusters both within the crystal and as isolated species. Calculations have been made with different bases in order to separate exchange, charge-transfer and induction energies. Calculations confirm the conclusion from perturbation theory that charge-transfer is an important contribution to three-body energies and gives a small four-body ene...
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ژورنال
عنوان ژورنال: Progress of Theoretical Physics
سال: 1967
ISSN: 0033-068X
DOI: 10.1143/ptp.38.995